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Perry Research Group
Publications

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Coherence-converted population transfer FTMW-IR double resonance spectroscopy of CH3OD in the OD -stretch region, Sylvestre Twagirayezu; David S. Perry, PhD; Justin L Neill; Matt T Muckle, J. Mol. Spectrosc., 262, 65-68 (2010), http://dx.doi.org/10.1016/j.jms.2010.05.003.

Vibrational coupling pathways in methanol as revealed by coherence-converted population transfer FTMW-IR double resonance spectroscopy, Sylvestre Twagirayezu, Trocia N. Clasp, David S. Perry, Justin L. Neill, Matt T. Muckle, Brooks H. Pate, J. Phys. Chem. A, 114, 6818-6828 (2010), http://dx.doi.org/10.1021/jp1019735.

Vibration–rotation alchemy in acetylene (12C2H2) at low vibrational excitation: From high resolution spectroscopy to fast intramolecular dynamics (invited article), David Perry, Anthony Miller, B. Amyay, A. Fayt and M. Herman, Mol. Phys. 108, 1115-1132 (2010), http://dx.doi.org/10.1080/00268971003660874.

A comparative ab initio study of torsion-inversion coupling in CH3NH2, CH3OH2+ and CH3CH2,  Ram S Bhatta, Amy Gao, David S Perry, A comparative ab initio study of torsion-inversion coupling in CH3NH2, CH3OH2+ and CH3CH2,  J. Mol. Struct.: THEOCHEM, 941, 22-29 (2009), http://dx.doi.org/10.1016/j.theochem.2009.10.033.

The Adiabatic Approximation as a Diagnostic Tool for Torsion-Vibration Dynamics (feature article), David S. Perry, J. Mol. Spectrosc. 257, 1-10 (2009), http://dx.doi.org/10.1016/j.jms.2009.05.002.

Torsion-vibration coupling in methanol: Diabatic behavior in the CH overtone region, David S. Perry, J. Phys. Chem. A 112, 215-223 (2008), http://dx.doi.org/10.1021/jp077269q

Conformational dependence of intramolecular vibrational redistribution in methanol, Pavel Maksyutenko, Oleg V. Boyarkin, Thomas R. Rizzo and David S. Perry, J. Chem. Phys., 126, 044311 (2007) (6 pages). http://link.aip.org/link/?JCPSA6/126/044311/1

Torsion-vibration coupling in  methanol: The adiabatic approximation and IVR scaling, Trocia N Clasp and David S Perry, J. Chem. Phys., 125, 104313 (2006). (9 pages). http://link.aip.org/link/?JCPSA6/125/104313/1

Fuel concentration measurements during flame spread in non-homogeneous gas mixtures, M. J. Kulis, D. S. Perry, F. Miller, J. Easton, and N. Piltch, Fourth Joint Meeting of the U.S. Sections of the Combustion Institute: Western States, Central States, Eastern States, Philadelphia, PA, United States, Mar. 20-23, 2005, B16/1 (2005). http://link.aip.org/link/?JCPSA6/122/044314/1

Vibrational overtone spectroscopy of jet-cooled methanol from 5000 to 14 000 cm-1, D. Rueda, O. V. Boyarkin, T. R. Rizzo, A. Chirokolava, and D. S. Perry, J. Chem. Phys. 122 (4), 044314/1 (2005).

Doppler-limited CW infrared cavity ringdown spectroscopy of the nu1 + nu3 OH + CH stretch combination band of jet-cooled methanol, S. Xu, J. J. Kay, and D. S. Perry, J. Mol. Spectrosc. 225 (2), 162 (2004).

Determination of reduced Hamiltonian parameters for the CD3OH isotopomers of methanol, L. Wang, Y.-B. Duan, R. Wang, G. Duan, I. Mukhopadhyay, D. S. Perry, and K. Takagi, Chem. Phys. 292 (1), 23 (2003).

Development of a diode laser diagnostic to measure methanol and water concentrations during a flame-spread event in microgravity, M. J. Kulis, D. S. Perry, and F. Miller, Abstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002, ANYL (2002).

Observation and analysis of high-J o1-e1 inter-state transitions in CH2DOH, I. Mukhopadhyay, D. S. Perry, Y.-B. Duan, J. C. Pearson, S. Albert, R. A. H. Butler, E. Herbst, and F. C. DeLucia, J. Chem. Phys. 116 (9), 3710 (2002).

Rotational and torsional analysis of the OH-stretch third overtone in 13CH3OH, A. Chirokolava, D. S. Perry, O. V. Boyarkin, M. Schmid, and T. R. Rizzo, J. Mol. Spectrosc. 211 (2), 221 (2002).

Torsion-rotation analysis of OH stretch overtone-torsion combination bands in methanol, D. Rueda, O. V. Boyarkin, T. R. Rizzo, I. Mukhopadhyay, and D. S. Perry, J. Chem. Phys. 116 (1), 91 (2002).

Diode laser diagnostic for use in microgravity, M. J. Kulis, D. S. Perry, and F. J. Miller, Abstracts of Papers, 222nd ACS National Meeting, Chicago, IL, United States, August 26-30, 2001, ANYL (2001).

Gravitational influences on flame propagation through non-uniform, premixed gas systems, F. J. Miller, J. Easton, H. D. Ross, A. Marchese, D. Perry, and M. Kulis, NASA Conf. Publ. (NASA/CO-2001-210826, Sixth International Microgravity Combustion Workshop, 2001), 321 (2001).

On the physical interpretation of torsion-rotational parameters for CH3OD isotopomers, L. Wang, Y.-B. Duan, I. Mukhopadhyay, D. S. Perry, and K. Takagi, Chem. Phys. 263 (2-3), 263 (2001).

Vibrational dependence of the torsional tunneling splitting and the a to b intensity evolution in the OH overtone spectra of CH3OH, M. A. Temsamani, L.-H. Xu, and D. S. Perry, Can. J. Phys. 79 (2/3), 467 (2001).

Intramolecular energy transfer in highly vibrationally excited methanol. IV. Spectroscopy and dynamics of 13CH3OH, A. Chirokolava, D. S. Perry, O. V. Boyarkin, M. Schmid, and T. R. Rizzo, J. Chem. Phys. 113 (22), 10068 (2000).

Sub-Doppler Infrared Spectra of the OH-Stretch Fundamental of 13C-Methanol, A. Chirokolava, D. S. Perry, and L.-H. Xu, J. Mol. Spectrosc. 203 (2), 320 (2000).

High-Resolution Infrared Spectra in the C-H Region of CH2F2: The n6 and 2n2 Bands, T. J. Cronin, X. Wang, G. A. Bethardy, and D. S. Perry, J. Mol. Spectrosc. 194 (2), 236 (1999).

Intramolecular energy transfer in highly vibrationally excited methanol. II. Multiple time scales of energy redistribution, O. V. Boyarkin, T. R. Rizzo, and D. S. Perry, J. Chem. Phys. 110 (23), 11346 (1999).

Intramolecular energy transfer in highly vibrationally excited methanol. III. Rotational and torsional analysis, O. V. Boyarkin, T. R. Rizzo, and D. S. Perry, J. Chem. Phys. 110 (23), 11359 (1999).

Intramolecular vibrational dynamics of highly excited methanol studied by rotationally resolved overtone spectroscopy, O. V. Boyarkin, D. S. Perry, and T. R. Rizzo, Book of Abstracts, 217th ACS National Meeting, Anaheim, Calif., March 21-25, PHYS (1999).

Torsion-vibration coupling in methanol, D. S. Perry, A. Chirokolava, Y. Ma, X. Wang, O. V. Boyarkin, and T. R. Rizzo, Book of Abstracts, 217th ACS National Meeting, Anaheim, Calif., March 21-25, PHYS (1999).

Double-resonance spectroscopic studies of IVR and conformational isomerism in vibrationally excited NH2OH and CH3OH, T. R. Rizzo, O. V. Boyarkin, M. Schmid, A. Chirokolava, and D. S. Perry, Book of Abstracts, 216th ACS National Meeting, Boston, August 23-27, PHYS (1998).

An internal coordinate model of coupling between the torsion and C-H vibrations in methanol, X. Wang and D. S. Perry, J. Chem. Phys. 109 (24), 10795 (1998).

Torsion - vibration coupling in methanol, X. Wang, Y. Ma, D. S. Perry, O. V. Boyarkin, and T. R. Rizzo, Book of Abstracts, 215th ACS National Meeting, Dallas, March 29-April 2, PHYS (1998).

Intramolecular energy transfer in highly vibrationally excited methanol. I. Ultrafast dynamics, O. V. Boyarkin, L. Lubich, R. D. F. Settle, D. S. Perry, and T. R. Rizzo, J. Chem. Phys. 107 (20), 8409 (1997).

Sub-Doppler infrared spectra and torsion-rotation energy manifold of methanol in the CH-stretch fundamental region, L.-H. Xu, X. Wang, T. J. Cronin, D. S. Perry, G. T. Fraser, and A. S. Pine, J. Mol. Spectrosc. 185 (1), 158 (1997).

Time scales and mechanisms of intramolecular energy redistribution, D. S. Perry, ACS Symp. Ser. 678 (Highly Excited Molecules), 70 (1997).

Energy randomization: How much of rotational phase space is explored and how long does it take? D. S. Perry, G. A. Bethardy, M. J. Davis, and J. Go, Faraday Discussions 102 (Unimolecular Reaction Dynamics), 215 (1996).

Multiple timescales in the intramolecular vibrational energy redistribution of highly excited methanol, L. Lubich, O. V. Boyarkin, R. D. F. Settle, D. S. Perry, and T. R. Rizzo, Faraday Discussions 102 (Unimolecular Reaction Dynamics), 167 (1996).

Timescales and mechanisms of intramolecular energy redistribution, D. S. Perry, Book of Abstracts, 212th ACS National Meeting, Orlando, FL, August 25-29, PHYS (1996).

Device for high-resolution frequency-modulated absorption spectroscopy of jet-cooled molecules, G. A. Bethardy and D. S. Perry, Rev. Sci. Instrum. 66 (4), 2829 (1995).

Direct absorption in supersonic free-jets, D. S. Perry and G. A. Bethardy, Techniques of Chemistry (New York) 23, 71 (1995).

The effect of the torsional barrier height on the acceleration of intramolecular vibrational relaxation (IVR) by molecular flexibility, D. S. Perry, G. A. Bethardy, and X. Wang, Berichte der Bunsen-Gesellschaft 99 (3), 530 (1995).

Random matrix treatment of intramolecular vibrational redistribution. II. Coriolis interactions in 1-butyne and ethanol, J. Go and D. S. Perry, J. Chem. Phys. 103 (13), 5194 (1995).

The role of molecular flexibility in accelerating intramolecular vibrational relaxation, G. A. Bethardy, X. Wang, and D. S. Perry, Can. J. Chem. 72 (3), 652 (1994).

Competing mechanisms for intramolecular vibrational redistribution in the n14 asymmetric methyl stretch band of trans-ethanol, G. A. Bethardy and D. S. Perry, J. Chem. Phys. 99 (12), 9400 (1993).

A free-jet infrared double resonance study of the threshold region of IVR. The n6, n1+n6, and 2n1 bands of propyne, J. Go, T. J. Cronin, and D. S. Perry, Chem. Phys. 175 (1), 127 (1993).

Frequency-resolved measurement of fast intramolecular vibrational energy redistribution (IVR) in the O-H stretch of gas-phase ethanol, G. T. Fraser, B. H. Pate, G. A. Bethardy, and D. S. Perry, Chem. Phys. 175 (1), 223 (1993).

Random matrix treatment of intramolecular vibrational redistribution. I. Methodology and anharmonic interactions in 1-butyne, D. S. Perry, J. Chem. Phys. 98 (9), 6665 (1993).

Rate and mechanism of intramolecular vibrational redistribution in the n16 asymmetric methyl stretch band of 1-butyne, G. A. Bethardy and D. S. Perry, J. Chem. Phys. 98 (9), 6651 (1993).

A high-resolution infrared-double-resonance technique for molecular-eigenstate spectroscopy in a free jet, J. Go and D. S. Perry, J. Chem. Phys. 97 (9), 6994 (1992).

Infrared spectra of the n2 and n16 bands in the methyl stretch region of jet-cooled 1-butyne, G. A. Bethardy and D. S. Perry, J. Mol. Spectrosc. 144 (2), 304 (1990).

Multipass cell for molecular beam absorption spectroscopy, D. Kaur, A. M. De Souza, J. Wanna, S. A. Hammad, L. Mercorelli, and D. S. Perry, Appl. Opt. 29 (1), 119 (1990).

Rotationally mediated intramolecular vibrational redistribution in jet-cooled trans-ethanol at 2990 cm-1, J. Go, G. A. Bethardy, and D. S. Perry, J. Phys. Chem. 94 (16), 6153 (1990).

Sliced-jet spectroscopy: a new technique for sub-Doppler spectroscopy of jet-cooled molecules, L. R. Mercorelli, S. A. Hammad, and D. S. Perry, Chem. Phys. Lett. 162 (4-5), 277 (1989).

Eigenstate-resolved vibrational state mixing in jet-cooled 1-butyne near 3333 cm-1, A. M. De Souza, D. Kaur, and D. S. Perry, Berichte der Bunsen-Gesellschaft 92 (3), 424 (1988).

Vibrational state mixing of individual rotational levels in 1-butyne near 3333 cm-1, A. M. De Souza, D. Kaur, and D. S. Perry, J. Chem. Phys. 88 (8), 4569 (1988).

Local-mode treatment of normal-mode molecules. 2. Application to chlorotrifluoromethane overtone spectra, A. M. De Souza and D. S. Perry, J. Phys. Chem. 90 (19), 4508 (1986).

On the nature of high tetrafluoromethane vibrational levels excited by proton energy loss spectroscopy, H. B. Levene and D. S. Perry, J. Chem. Phys. 84 (8), 4385 (1986).

Conductivity in semiconductors induced by vibrational-to-electronic energy transfer, I. Last, T. F. George, and D. S. Perry, Mater. Lett. 2 (4B), 315 (1984).

Excitation of localized oscillations: the high vibrational overtone spectrum of sulfur hexafluoride, H. B. Levene and D. S. Perry, J. Chem. Phys. 80 (5), 1772 (1984).

Local mode treatment of normal mode molecules: application to dichlorodifluoromethane overtone spectra, D. E. Brabham and D. S. Perry, Chem. Phys. Lett. 103 (6), 487 (1984).

Spectroscopy and intramolecular relaxation of methyl salicylate in its first excited singlet state, J. W. Kuper and D. S. Perry, J. Chem. Phys. 80 (10), 4640 (1984).

Comparison of the symmetrized Cartesian and angular momentum basis sets to describe vibrationally excited states in spherical top molecules, H. B. Levene and D. S. Perry, J. Chem. Phys. 79 (9), 4397 (1983).

High overtone vibrational spectrum of sulfur hexafluoride: evidence for localized vibrations, H. B. Levene and D. S. Perry, Time-Resolved Vib. Spectrosc., [Proc. Int. Conf. TRVS], 117 (1983).

Comparison of reagent translation and vibration on the dynamics of the endothermic reaction atomic strontium + hydrogen fluoride, A. Gupta, D. S. Perry, and R. N. Zare, J. Chem. Phys. 72 (11), 6250 (1980).

Effect of reagent translation on the dynamics of the exothermic reaction atomic barium + hydrogen fluoride, A. Gupta, D. S. Perry, and R. N. Zare, J. Chem. Phys. 72 (11), 6237 (1980).

Use of lasers in the study of state-to-state reaction dynamics: Ba,Sr + HF, D. S. Perry, A. Gupta, and R. N. Zare, Proceedings of the Technical Program - Electro-Optics/Laser Conference & Exposition, 141 (1980).

Energy distribution among reaction products. IX. Atomic fluorine + molecular hydrogen, molecular hydrogen-d1 and molecular deuterium, D. S. Perry and J. C. Polanyi, Chem. Phys. 12 (4), 419 (1976).

An experimental test of the Bernstein-Levine theory of branching ratios, D. S. Perry and J. C. Polanyi, Chem. Phys. 12 (1), 37 (1976).

Studies in the dynamics of reactions A + BC.tautm. AB + C, D. S. Perry, Ph.D. Thesis, The University of Toronto, 1975.

Location of energy barriers. VI. Dynamics of endothermic reactions, AB + C, D. S. Perry, J. C. Polanyi, and C. W. Wilson, Jr., Chem. Phys. 3 (3), 317 (1974).

Test of the procedure for obtaining detailed endothermic rate constants from microscopic reversibility, D. S. Perry, J. C. Polanyi, and C. W. Wilson, Jr., Chem. Phys. Lett. 24 (4), 484 (1974).

Effect of changing reagent energy on reaction probability and product energy-distribution, A. M. G. Ding, L. J. Kirsch, D. S. Perry, J. C. Polanyi, and J. l. Schreiber, Faraday Discussions of the Chemical Society 55, 252 (1973).

Location of energy barriers. V. Scaling the energy surface for AB+CD.far. AC+BD, D. S. Perry and J. C. Polanyi, Can. J. Chem. 50 (23), 3916 (1972).



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